Very odd. Thought I'd picked up a puncture on Saturday morning. The tyre was just suddenly very rim-bangingly soft. Broke my tyre levers trying to get the tyre off, so used the stop-every-now-and-then-to-pump-it-up method of getting home.
Yesterday I went to sort it, and found there was still air in it, around the same as when I'd parked it in the garage. So I pumped it up to about 100psi and checked a few hours later. Still rock solid.
Checked this morning. Still rock solid.
Ride to work, rim bangingly soft just as I get to the office. My guess is faulty valve... Going to chuck in the spare tube I think.