So, I finished re-assembling my hub gear at about 1am last night. Rode it around outside on the road for 30 seconds to prove it worked. Put it away and go to bed happy.
This morning - front tyre flat. What's more, the tyre is off the rim and the tube has exploded along a ~4 inch section. The tyre bead is intact, but it's pulled free superficial rubber from the bead area...
Can't find any of the fat 700c tubes I bought with the tyres, so I grab a thin 700 from the flat pile on the grounds that it doesn't make much difference.
Fix flat, put in tyre, start to pump... HSSSSSSS
Fix flat just next to first flat, put in tyre, start to pump... HSSSSSSS
Abandon and get on MTB (from 15 minutes early, now running 10 minutes late).
A bit concerned that either the rim or the tyre is damaged as otherwise hard to explain how it could have exploded from a 'steady state'. Pressure ~80psi of a recommended 50-95.
So, still no luck riding the white bike... AAARGH.